首届人类世科学大会在西安成功举办

2023年6月17—18日,首届“人类世科学大会”在古都西安成功举办,本次会议由中国地质学会主办,中国地质学会人类世研究分会、中国科学院地球环境研究所、黄土科学全国重点实验室（筹）、陕西省基础学科（地球系统科学）研究中心共同承办。     

Acidities of confined water in interlayer space of clay minerals

The acid chemistry of confined waters in smectite interlayers have been investigated with first principles molecular dynamics (FPMD) simulations. Aiming at a systematic picture, we establish the model systems to take account of the three possible controlling factors: layer charge densities (0 e, 0.5 e and 1.0 e per cell), layer charge locations (tetrahedral and octahedral) and interlayer counterions (Na⁺ and Mg²⁺). For all models, the interlayer structures are characterized in detail. Na⁺ and Mg²⁺ show significantly different hydration characteristics: Mg²⁺ forms a rigid octahedral hydration shell and resides around the midplane, whereas Na⁺ binds to a basal oxygen atom and forms a very flexible hydration shell, which consists of five waters on average and shows very fast water exchanges. The method of constraint is employed to enforce the water dissociation reactions and the thermodynamic integration approach is used to derive the free-energy values and the acidity constants. Based on the simulations, the following points have been gained. (1) The layer charge is found to be the direct origin of water acidity enhancement in smectites because the neutral pore almost does not have influences on water dissociations but all charged pores do. (2) With a moderate charge density of 0.5 e per cell, the interlayer water shows a pKa value around 11.5. While increasing layer charge density to 1.0 e, no obvious difference is found for the free water molecules. Since 1.0 e is at the upper limit of smectites’ layer charge, it is proposed that the calculated acidity of free water in octahedrally substituted Mg²⁺-smectite, 11.3, can be taken as the lower limit of acidities of free waters. (3) In octahedrally and tetrahedrally substituted models, the bound waters of Mg²⁺ show very low pKa values: 10.1 vs 10.4. This evidences that smectites can also promote the dissociations of the coordinated waters of metal cations. The comparison between the two Mg²⁺-smectites reveals that different layer charge locations do not lead to obvious differences for bound and free water acidities.     

古沙漠记录的沉积体系及层序地层研究进展——以鄂尔多斯盆地白垩系为例

鄂尔多斯盆地白垩纪古沙漠沉积地层主要为冲积扇、湖泊、河流、三角洲及沙漠沉积体系.风成沉积和沙漠沉积、风成沉积体系和沙漠沉积体系等概念有必要予以区分.基准面变化是沙漠和河流、湖泊等其他陆相地层对比的基础.鄂尔多斯盆地志丹群划分为上下两个三级层序单元,反映了两期古沙漠由风成沉积强盛期到衰退期的演化,且每个层序可划分为低位、...     

浙江早古生代孢粉型化石的研究

在浙江西北部早寒武世荷塘组、晚寒武世华严寺组、早奥陶世宁国组、晚奥陶世长坞组和文昌组、早志留世霞乡组、河沥溪组和康山组、中志留世唐家坞组中发现孢粉型化石,孢粉型化石包括疑源类,隐花(陆生)植物孢子类型等,计66属、112种、31未定种。同时讨论了这9个层位孢粉型化石的组合特征、地质时代及其沉积环境。     

聚油古地貌成因类型及其有利成藏条件分析——以鄂尔多斯盆地上里塬地区前侏罗纪古地貌为例

运用地层厚度印模法（延9＋延10＋富县组地层厚度）恢复出了陇东上里塬地区前侏罗纪古地貌形态,其形态为一级甘陕古河呈近东西向分布,二级庆西古河位于研究区南部向北注入甘陕古河,研究区的北部和南部分别发育姬塬和演武高地,在高地和河谷的过度带分别发育姬塬南斜坡和演武北斜坡,此外,在一级河谷中央还发育有河间丘,在斜坡上发育残丘、...     

青藏高原地面有效辐射变化及其对表层土温的影响

利用青藏高原格尔木、狮泉河、昌都日射站及中国科学院冰冻圈观测研究站的观测资料,分析了高原有效辐射的变化,在此基础上结合土壤温度资料讨论了高原北部有效辐射的变化对表层土壤热状况的影响.结果显示：1）青藏高原有效辐射变化因所处的区域不同而异,高原东北部、西部及高原腹地有效辐射总体呈减小的趋势,高原东南部有效辐射呈增大的趋势...     

Comparison of Results of Recent Seismic Profiles with Tectonic Models of the North China Craton

The geometry and timing of amalgamation of the North China craton(NCC) have been controversial,with three main models with significantly different interpretations of regional structure,geochronology,and geological relationships.The model of Zhao G C et al.suggests that the eastern and western blocks of the NCC formed separately in the Archean,and an active margin was developed on the eastern block between 2.5 and 1.85 Ga,when the two blocks collided above an east dipping subduc-tion zone.The model of Kusky ...     

Distribution of Arsenic in Sewage Irrigation Area of Pearl River Delta,China

The aim of the present work is to investigate the distribution of arsenic(As) in sewage ir-rigation area,to deduce the migration and transformation mechanism of As in soil and groundwater,and to infer the source of As in soil and groundwater.This study is carried out in a sewage irrigation area of the Pearl River Delta,China.Surface water samples,soil samples,and groundwater samples from sewage irrigation area were analyzed for As and other elements.As contents in water samples were analyzed by hydride gene...     

Deposition Process of Dust Microparticles from Aerosol to Snow-Firn Pack on Glacier No. 1 in Eastern Tianshan Mountains, China

Samples were continuously collected from aerosol, fresh snow, and snow pits on Glacier No. 1 at Urumqi River source in eastern Tianshan (天山) Mountains. The deposition processes and the characteristics of mineral dust microparticles from aerosol to fresh snow, and then evolution to the snow pit were determined. Total dust microparticle concentration in the surface snow and aerosol showed a similar temporal variation trend, which was strongly associated with regional and local at-mospheric circulation in the ...     

Tectonics and Mechanisms of Uplift in the Central Uplift Belt of the Huimin Depression

The Huimin (惠民) depression is a third-level tectonic element of the Bohai (渤海) Bay basin in eastern China. The central uplift belt is the most important oil and gas accumulation zone in the depression, but the lack of adequate geological studies in the area has greatly hindered exploration and development. In this article, using seismic data, fracture mechanics, and a combination of data on fault growth indices and fault throws, we present an analysis of tectonic activity in the central uplift belt and adja...